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Enantioselective Total Synthesis of Fortimicin B
Asymmetric total synthesis of fortimicin B was realized in 12 steps (LLS) from readily available starting materials. The fortamine fragment was synthesized in a concise …
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Discovery and enantioselective total synthesis of antitumor …
The enantioselective total synthesis was efficiently accomplished from the key intermediate (S)- 6 with three contiguous stereocenters in 5 steps and the synthetic 1 induced …
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Enantioselective total syntheses of melotenine-, voacafrine-, …
Herein, we present the successful design and development of a new strategy for the first enantioselective total synthesis of C11-demethoxymelotenine (2), 3-oxotabersonine …
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Enantioselective route to an AE-ring intermediate in the total ...
Herein, we disclose the development of an enantioselective route to (–)- 5-β for the total synthesis of (–)- 1. Enantioselective intermolecular Mannich, Lewis acid-mediated …
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Enantioselective Total Synthesis of Bipolarolides A and B
Bipolarolides A and B are members of the ophiobolin family of sesterterpenes, characterized by their intricate cage-like structures. Herein we report a concise asymmetric …
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Enantioselective total synthesis of lycoposerramine …
B Second-generation synthesis of chiral amine fragment 23 from (R)-pulegone. C N -deletion of 22 and total synthesis of lycoposerramine W 6. D Selected results from benzylic …
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Enantioselective Total Synthesis of (−)‐Cephalotanin B
Cephalotaxus diterpenoids are attractive natural products with intriguing molecular frameworks and promising biological features. As a structurally unusual member, (−) …
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